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A Complete Guide to Duplex and Super Duplex Stainless Steel for Industrial Applications

A Complete Guide to Duplex and Super Duplex Stainless Steel for Industrial Applications
A Complete Guide to Duplex and Super Duplex Stainless Steel for Industrial Applications

Duplex and Super Duplex steels are highly reputed in terms of their incredible strength and resistance to corrosion and hence are the most appropriate when it comes to the rough and tough conditions. Their combination in most cases aims at acquiring the benefits of both austenitic and ferritic structures. They are very durable and very resistant to corrosion. Such sectors as oil and gas, chemical, marine, or any other of such alloys offers a stable performance in harsh conditions. In the case of Duplex vs Super Duplex, it is quite hard to say which is superior, they both are very strong and the corrosion resistance is also very high; however Super Duplex has a slight corrosion resistance and strength than the duplex steel. In general, these materials will offer a long life and reliable performance of your applications.

What is the difference between duplex and super duplex stainless steels?

The difference between Duplex and Super duplex stainless steel is their structure, strength, and corrosion resistance. Their composition is in moderate proportions of austenitic and ferritic phases and Super Duplex has more alloy composition especially chromium, molybdenum and nitrogen. This enhanced degree of structure gives Super Duplex with an enhancement in mechanical power and resistance against pitting, crevice corrosion, and stress corrosion cracking. Whereas Duplex has a high degree of functionality in most of the demanding applications, Super Duplex is selected in the more hostile environments where pressure, temperature and chloride tend to be elevated. The differences enable each grade to have individual applications in the specific industry demands, which are durability and protection against corrosion, which are needed.

In city infrastructure, steel pipes run underground for water and gas distribution. In buildings, they’re often called out as conduit to shield electrical wiring. Thanks to high strength at relatively low weight, pipe also finds its way into bicycle frames and automotive components. You’ll see steel pipes in refrigeration and HVAC, heating and plumbing systems, and in everyday fixtures like flagpoles and street/area light poles.

Microstructure and Strength Properties

  • Duplex Steel:  The duplex steel (UNS S31803)  is characterized by a balanced austenite and ferrite microstructure, which provides it with a great strength and toughness combination. This is a two-phase structure that is resistant to cracking and stress, but is easy to weld. As a result of this balance, Duplex steel properties have a larger yield strength compared to other stainless steels, which is why it is applicable in application of both durability and reliability.
  • Super Duplex Steel: The Super Duplex steel is a continuation of the ferrite austenite balance but with a higher content of alloy making it even stronger. It has a better microstructure that provides high deformation and stress-related failure resistance. Super Duplex steel has much more yield strength, and thus, is perfect in very demanding conditions where structural integrity is paramount.

Corrosion Resistance in Chloride Environments

  • Duplex Stainless Steel: Duplex stainless steel is also good in a chloride environment since its mixed structure can be used to prevent stress corrosion cracking. It is also pittable resistant, hence, suitable when used in seawater, chemical processing, and such like environments. That is why high-pressure duplex or UNS S31803 Pipe is widely used in industries that require stable and long-term performance.
  • Super Duplex Steel: Super Duplex steel contains more alloy, which provides it with even superior resistance to stress corrosion cracking as well as pitting. It is also stable and durable in extremely harsh chloride conditions, and thus corrosion-resistant duplex steel is the choice in the offshore, marine and heavy industry.

Duplex vs Super Duplex Stainless Steel Comparison

To compare these the steel it’s necessary to check the composition and other properties that make them different from each other.

Property / FeatureDuplex Stainless Steel 2205 (UNS S32205)Super Duplex Stainless Steel (UNS S32750 / S32760)
MicrostructureBalanced ferrite + austeniteEnhanced ferrite + austenite with higher alloy content
StrengthHigh yield strength (higher than 300 series SS)Very high strength (higher than Duplex 2205)
Corrosion ResistanceExcellent resistance to chloride stress corrosion crackingSuperior resistance to pitting, crevice corrosion, and SCC
Alloy ContentModerate chromium, molybdenum, nitrogenHigher chromium, molybdenum, and nitrogen
UNS DesignationS32205S32750 / S32760
WeldabilityGoodGood but more sensitive due to richer alloy content
Ideal EnvironmentModerate to high chloride exposureExtremely high chloride or highly corrosive conditions
CostMore economicalHigher cost due to increased alloy levels

Price Difference Between Duplex and Super Duplex

Both Duplex and Super Duplex have better resistance towards corrosion than normal steel. However, the super duplex grades are especially good in terms of resistance to pitting. It has a high amount of chromium content that is around 27% more compared to standard duplex grades. To balance the chromium in the steel, it was made with high nickel elements to balance it. Nickel is expensive and its price also fluctuates; on the other hand, molybdenum is a rare and high-priced element. As a result, super duplex is more expensive than duplex, and it also varies from country to country.

Applications of Duplex Stainless Steel in Modern Industries

Lightweight applications are predominantly done with duplex steel. There are numerous Duplex stainless steel applications utilized in various industries as listed below.

  • Offshore Oil and Gas Platforms :
    Due to high pressure and anti-corrosion in the face of seawater, duplex pipes and tubes are common in offshore situations. They are needed in the process systems and water injection lines where the strength and the reliability during the long term is important. Learn more here: 
  • Marine Systems and Desalination :
    Duplex pipes are also very resistant to brine and saltwater in desalination plants. They are applied in the brine discharge lines and seawater handling lines and they are smooth in operation in the highly corrosive environment.
  • Chemical and Petrochemical Unit :
    Heat exchangers and pressure pipes requiring corrosive chemicals are made of duplex steel. It is very strong and stable and thus suitable in reactors, refineries and fluid transfer lines.

Applications of Super Duplex Stainless Steel in Extreme Environments

Now, here are the different industries that use Super Duplex stainless steel applications according to their requirements.

  • Underwater Deepwater Extraction Systems
    Most of the applications of the Super Duplex pipe are used in deepwater applications involving extreme pressure and where there are high levels of chloride. UNS S32750 and Super Duplex 2507 are highly powerful and corrosive and thus would be appropriate in the flowline systems and extraction systems that are below the sea.
  • High Chloride Systems
    Even in the high chloride environments, super Duplex pipes perform well. They are used in reverse osmosis systems which are operated with aggressive brine and offshore risers being in touch with seawater and at high pressure. The applications also have the increased cracking and pitting resistance of the material.
  • Cooling and firefighting lines 
    The option of cooling systems and firewater pumps that rely on the sea water or a salty fluid are Super Duplex pipes. Their resistance to corrosion is very high and they can be applied to cooling circuits, heat rejection lines and the firefighting networks. UNS S32750 pipe shall ensure a long-term service that will be reliable and with low maintenance cost.

Why Industries Prefer Duplex and Super Duplex Over Standard Stainless Steel

Most of the industry uses these two steel rather than using normal steel. Here is the detailed comparison of Duplex and Super Duplex Over Standard Stainless Steel.

FeatureDuplex Stainless SteelSuper Duplex Stainless SteelStandard Stainless Steel (304/316)
StrengthHigher strength than standard stainless steelVery high strength, ideal for extreme conditionsModerate strength
Corrosion ResistanceGood resistance to chlorides and stress corrosion crackingExcellent resistance to pitting, crevice corrosion, and chloridesLimited resistance in chloride environments
MicrostructureBalanced ferrite + austeniteEnhanced ferrite + austenite with higher alloy contentAustenitic structure
Best Use EnvironmentsMarine, chemical, and moderate chloride exposureHarsh offshore, subsea, and high-chloride applicationsGeneral use, low to mild corrosion
Cost EfficiencyMore economical than Super Duplex with strong performanceHigher cost due to rich alloy contentGenerally more affordable
DurabilityLong service life in corrosive conditionsExceptional durability in severe environmentsGood durability but reduced in chlorides
Key AdvantageStrong balance of strength and corrosion resistanceMaximum performance in toughest environmentsVersatile but less suitable for harsh conditions

How to Select the Right Grade for Your Project

When choosing duplex and super duplex stainless steel pipes. By remembering these points, the appropriate grade would be chosen to be used in long-term operation.

  • Chloride Level Check
    The selection of the correct grade would depend on the level of chloride in the environment. An increase in chloride exposure requires more resistant to corrosion such as Duplex and Super Duplex stainless steel to avoid pitting and cracking in the long-term.
  • Pressure Rating 
    Always ensure that the pipe is matched with the operating pressure of the system. Super and duplex stainless steel contain a greater strength and therefore are used in high pressure lines without fear of deformation and leakage.
  • Temperature
    Material stability can be influenced by temperature variation. The grades are effective in both high and varying temperatures, which contributes towards saving EPC teams failures due to thermal stress after prolonged operation.
  • Budget vs Lifespan Balance
    Although Duplex and Super duplex are slightly more expensive to install initially, they offer a longer service life and less maintenance hence they are a more cost effective option when it comes to projects with long periods of service.

Final Thoughts

Duplex and Super Duplex steels are still the best in strength, corrosion resistant and convenient operation in hard condition. They are a safe choice when it comes to sensitive industrial system since it can work under extreme pressure, exposure to harsh chemical substances, and chloride based environment. In case you do not know which grade is the right one or need to have some technical information, you may ask Duplex or Super Duplex pipe specifications to receive the professional help depending upon your project.

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